PV1 is correct. Here's a simplistic video followed by a detailed article.
http://insideevs.com/video-complex-operation-of-mitsubishi-outlander-phev-dumbed-down-to-the-extreme/
The engine is coupled to a generator and also turns the front drive motor through a clutch, enabling electric-only AWD, engine-tied cruising, and also use of the engine as a generator only. It's similar to the Chevy VOLT, but with a second electric drive for the other axle!
http://www.hybridcars.com/mitsubishi-reveals-more-info-on-its-outlander-phev/
I would've liked to see a simpler, cheaper approach that used only two motors, opening the range for FWD stripper and the premium AWD version. I guess high demand vs low supply dictated a single variant at the higher content/price level, and in using just a variant of the i-MiEV motor, they needed two of 'em to be able to push the heavy beast! A FWD version might've retained 3rd row seating, which could've been a much more economical offering than the upcoming Chrysler Pacifica Hybrid for those who need more than 5 seats.
While on the speculative note, has any maker offered the simplest plug-in hybrid of all- a single motor in the driveline with clutches on both ends, enabling EV mode and also functionality like both a Series and Parallel Hybrid? The Prius met that mission, but with two motor/generators and a very complicated gearset, while the 2nd generation Honda IMA came very close with their dual-clutch IMA, though still with a relatively weak motor.
ie: Declutch the engine for motor regen without engine braking, re-engage for engine braking during descent with full regen if still accelerating downhill, and declutch between motor and driveline for stationary or coastdown generator operation. For 'mountain mode', have the engine provide excess power for both traction and a bit of regen to fill the battery prior to an ascent.